Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO₂ levels     

Shane M. Ohline  Malcolm R. Reid  Shamus L.G. Husheer  Kim I. Currie  Keith A. Hunter 《Marine Chemistry》2007

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].  相似文献   

Bringing GPS into harsh environments for fully automated deformation monitoring     

Jason Bond  Adam Chrzanowski  Don Kim 《GPS Solutions》2008,12(1):1-11

Engineering projects that require deformation monitoring frequently utilize geodetic sensors to measure displacements of target points located in the deformation zone. In situations where control stations and targets are separated by a kilometer or more, GPS can offer higher precision position updates at more frequent intervals than can normally be achieved using total station technology. For large-scale deformation projects requiring the highest precision, it is therefore advisable to use a combination of the two sensors. In response to the need for high precision, continuous GPS position updates in harsh deformation monitoring environments, a software has been developed that employs triple-differenced carrier-phase measurements in a delayed-state Kalman filter. Two data sets were analyzed to test the capabilities of the software. In the first test, a GPS antenna was displaced using a translation stage to mimic slow deformation. In the second test, data collected at a large open pit mine were processed. It was shown that the delayed-state Kalman filter developed could detect millimeter-level displacements of a GPS antenna. The actual precision attained depends upon the amount of process noise infused at each epoch to accommodate the antenna displacements. Higher process noise values result in quicker detection times, but at the same time increase the noise in the solutions. A slow, 25 mm displacement was detected within 30 min of the full displacement with sigma values in E, N and U of ±10 mm or better. The same displacement could also be detected in less than 5 h with sigma values in E, N and U of ±5 mm or better. The software works best for detecting long period deformations (e.g., 20 mm per day or less) for which sigma values of 1–2 mm are attained in all three solution components. It was also shown that the triple-differenced carrier-phase observation can be used to significantly reduce the effects of residual tropospheric delay that would normally plague double-differenced observations in harsh GPS environments.

Don KimEmail:

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"盆地聚集效应"与矿业城市经济的可持续发展   总被引：1，自引：0，他引：1  

李守义  刘畅  王殿华  张婷婷  楚颖  张璟 《世界地质》2008,27(1):110-112

很多依赖矿产资源发展起来的矿业城市如今陷入了困境,原因在于其发展模式存在结构上的缺陷.在矿产资源日益稀缺、竞争不断加剧的时代,仅仅依靠矿产资源求发展是一种不可持续的模式.矿业城市应该构筑政策、环境、人才和市场等盆地,利用"盆地聚集效应",积极引进外部资源,完善产业结构,实现矿业城市经济的可持续发展.  相似文献   

A bootstrap based space–time surveillance model with an application to crime occurrences     

Youngho Kim  Morton O’Kelly 《Journal of Geographical Systems》2008,10(2):141-165

This study proposes a bootstrap-based space–time surveillance model. Designed to find emerging hotspots in near-real time, the bootstrap based model is characterized by its use of past occurrence information and bootstrap permutations. Many existing space–time surveillance methods, using population at risk data to generate expected values, have resulting hotspots bounded by administrative area units and are of limited use for near-real time applications because of the population data needed. However, this study generates expected values for local hotspots from past occurrences rather than population at risk. Also, bootstrap permutations of previous occurrences are used for significant tests. Consequently, the bootstrap-based model, without the requirement of population at risk data, (1) is free from administrative area restriction, (2) enables more frequent surveillance for continuously updated registry database, and (3) is readily applicable to criminology and epidemiology surveillance. The bootstrap-based model performs better for space–time surveillance than the space–time scan statistic. This is shown by means of simulations and an application to residential crime occurrences in Columbus, OH, year 2000.  相似文献   

Estimating hydraulic conductivity using grain-size analyses, aquifer tests, and numerical modeling in a riverside alluvial system in South Korea   总被引：2，自引：0，他引：2  

Jae-Yeol Cheong  Se-Yeong Hamm  Hyoung-Soo Kim  Eun-Joung Ko  Kyounghee Yang  Jeong-Hwan Lee 《Hydrogeology Journal》2008,16(6):1129-1143

Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10^?4 m s^?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10^?4 m s^?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10^?6 m s^?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system.  相似文献   

数字地质调查系统中空间数据库建库流程 关键技术的解决方案   总被引：3，自引：0，他引：3  

李丰丹  李超岭  刘畅  吕霞 《地质通报》2008,27(7):980-985

空间数据库建库流程是数字地质调查系统总体技术流程的一个重要组成部分。针对地质人员实际工作量等方面的几个关键技术问题提出了详细的解决方案．并在数字地质调查系统的软件系统中以辅助建库工具、辅助检查工具、数据检索工具的形式加以实现。为建库提供了技术保障,保证了数据的质量,有效地提高了地质人员对地质调查系统的应用能力和建库的效率。  相似文献   

中国数字地质调查系统的基本构架 及其核心技术的实现   总被引：6，自引：0，他引：6  

李超岭  杨东来  李丰丹  刘畅  刘修国  于庆文  吕霞 《地质通报》2008,27(7):923-944

数字地质调查系统是贯穿整个地质矿产资源调查全过程的软件,涵盖地质矿产调查、矿产资源勘查、矿体模拟、品住估计、资源量估算、矿山开采系统优化等内容。考虑数字地质调查系统的应用技术层面,从数据“层”模型、数据流“池”技术、不同阶段数据模型继承技术、数据互操作技术等几个方面讨论了核心技术及其实现,通过基于无缝一体化技术的数据采集、管理、综合处理与成果表达,在实体或矿块的矿床建模技术与品住估计、储量估算等方面展现了全地质调查过程的数字化,不但为地质人员应用高新技术降低了门坎,而且极大地提高了研究精度和效率,丰富了成果的表现形式和服务形式。随着数字地质调查系统的完善和应用水平的提高,数字地质调查系统将成为中国地质调查的主流软件体系。  相似文献   

The contact binary system YY Eri     

E. Budding  C-H. Kim  O. Demircan  Z. Müyesseroğlu  K. Saijo  T. Banks 《Astrophysics and Space Science》1996,246(2):229-242

Relatively new and unanalysed photometric data-sets of the contact binary system YY Eri are presented. The light curves have been analysed using information limit optimization techniques, and the Binary Maker program of Bradstreet (1992).Comparison of the results allows insight into determinacy questions affecting the W UMa type of light curve, which relates to our general understanding of contact binaries. A limiting contact configuration cannot be ruled out on the basis of empirical data-analysis alone.Very careful analysis of the photospheric flux distribution over the surface of the Sun may help establish appropriate values of the gravity brightening parameter for cool dwarf stars. At present, however, empirical photometric information on contact binaries is non-discriminatory: i.e. alternative cosmogonies can find alternative support from available evidence. The implication is then for more and better observational data to allow better real independent parameter determination.  相似文献   

Pulsar radio emission     

Hsiang-Kuang Chang  Wolfgang Kundt 《Astrophysics and Space Science》1993,209(2):313-322

Radio emission by pulsars is calculated from first principles. In an almost current-free magnetosphere, the two charged components (of the unsteadily escaping pair plasma) have different (and varying) bulk Lorentz factors. Curvature radiation emitted by the more energetic component is thus locally coherent, (so-called antenna mechanism). Strong enough seed signals cause the relativistically streaming charges to enhance their radiation, via an induced drift that can largely exceed the curvature drift. This amplification mechanism is similar to - but different from - that of a maser; we call it a MAIDER. Maximal amplification occurs at an (emission) altitude where the two components have sufficiently separated in energy though not yet separated too strongly in space.  相似文献   

Gamma-ray bursts from nearby neutron stars     

Wolfgang Kundt  Hsiang-Kuang Chang 《Astrophysics and Space Science》1993,200(1):151-162

We interpret the puzzling-ray bursts as emitted by cooling sparks from the surface of spasmodically accreting, old neutron stars. Their spiky, anisotropic radiation is oriented w.r.t. the galactic disk via interstellar accretion, whose orbital angular momentum tends to counteralign with the galactic spin; in this way, larger source numbers in directions of the galactic disk are compensated by smaller beaming probabilities, resulting in a near-isotropic arrival distribution, as observed by BATSE. The source distances range between 10 pc and 500 pc. Their radiated energies are of order 10³⁵ erg, corresponding to accreted clumps (blades) of typical mass 10¹⁵ g per burst. Magnetic surface field strengths range between 10¹⁰ and 10¹² G, somewhat weaker than those of newborn neutron stars.  相似文献